Description
Rather than broadly discussing a variety of environmental problems, the author focuses on principles throughout the text, leading students to understand processes and how knowledge of those processes can be applied to environmental problem solving. A wide variety of case studies and quantitative problems accompany each chapter, giving each instructor the flexibility to tailor the material to his/her course. Many problems have no single correct answer, illustrating the analytical nature of solving real-world environmental problems.
The Atom / Chemical Bonding / Atomic and Molecular Weights / Measurement of Concentration / Types of Chemical Reactions / Determining and Balancing a Chemical Equation / Gases / Structure and Properties of Water / Box Models and Geochemical Cycles / Questions and Problems
2. Equilibrium Thermodynamics and Kinetics
The Laws of Thermodynamics / Equilibrium Thermodynamics / Calculation of Activity Coefficients / Aqueous Complexes / Measurement of Disequilibrium / Kinetics / Water-Chemistry Computer Models / Case Studies / Questions and Problems
3. Acid-Base Equilibria
Definition of Acids and Bases / The Dissociation of Water and pH / pH of Natural Waters / Amphoteric Hydroxides / Acidity and Alkalinity / Acidity and Alkalinity Titrations / Buffers / Mineral-Water Reactions / Acid-Base Equilibria Case Studies / Questions and Problems
4. Oxidation-Reduction Reactions
Basic Principles / Oxidation-Reduction Diagrams / The Role of Microorganisms in Oxidation-Reduction Reactions / Oxidation-Reduction Processes in Natural Systems / Questions and Problems
5. Carbon Chemistry
Basic Structures and Naming of Organic Compounds / Carbon Compounds in the Environment / Humic Substances / Soil and Marine Organic Matter / Fossil Fuels / Natural Carbon Inputs to Surface and Ground Waters / Geochemical and Biochemical Processes That Control the Concentration of Organic Chemicals in Water / Questions and Problems
6. Isotopes
Radioactive Isotopes / Stable Isotopes / Questions and Problems
7. Environmental Mineralogy
Basic Mineralogy / Basic Silicate Structures / Clay Minerals / Zeolites / The Asbestos Minerals / Crystalline and Amorphous Silica / Mineral-Microorganism Interactions / Questions and Problems
8. The Atmospheric Environment
Properties of the Earth’s Atmosphere / Air Pollution / Greenhouse Gases and Climate Change / Ozone / Radon / Rainwater Chemistry / Chemistry and Sources of Atmospheric Particulates (Aerosols) / Questions and Problems
9. The Continental Environment
The Hydrologic Cycle / Weathering / Geochemistry of Surface and Ground Waters / Adsorption-Desorption Processes / Complex Formation and Chelation / Metals / Nonmetals / Questions and Problems
10. The Marine Environment
Physical Aspects of the Open Ocean / Chemical Composition of the Open Ocean / Seawater Chemistry / Geochemistry of Marine Sediments / The Marginal Marine Environment / Questions and Problems
Appendix I: Electronic Structure and Valences of the Elements
Appendix II: Standard State (298.15 K, 105 Pa) Thermodynamic Data
Appendix III: Ionic Radii in Å for Different Charges and Coordination Numbers
Appendix IV: Piper Diagram for Water Chemistry Problems
Answers to Selected Problems




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